Abstract

A novel gas phase treatment system (contaminant absorption and recovery [CAR]) for removal and subsequent recycling of gas phase VOCs from soil vapor extraction/gas stripping systems has been developed. Gas phase removal efficiencies using a packed column contactor exceed 99 percent The VOC-laden absorption fluid is subsequently vacuum-stripped of the VOCs, allowing potential condensation into liquid solvent concentrates. Partition coefficients for trichloroethylene (TCE) in triethylene glycol (TEG) ranged to ca. 5.0 mole fraction gas/mole fraction liquid, indicating a significant capacity for removal from the gas phase. Results of pilot-scale operation indicate favorable removal efficiencies and cost-effective performance in comparison to GAC or thermal destruction processes. System mass transfer coefficient predictions were done, using a variety of mathematical models and compared to experimental results. A modified Mangers and Ponten correlation was found to describe system mass transfer coefficients w...

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