Abstract
SummaryThe article herein briefly introduces the story of the birth of click chemistry and its evolution after that. A new angle to interpret click reactions was proposed using the “reactivity‐availability‐functionality” trilogy. CuAAC (Copper‐catalyzed azide‐alkyne cycloaddition), the most popular click reaction by far, was revisited along with the thiol‐ene, metal‐free AAC, SuFEx (Sulfur(VI) fluoride exchange) and the lately discovered diazotransfer process. By encountering more and more near‐perfect reactions, click chemistry is evolving and expanding on the fringe of the chemistry and different scientific disciplines, destination unknown.
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