Cleavage of carbon-sulfur bonds in thiolato ligands in osmium carbonyl cluster compounds. The synthesis and structural characterization of H2Os6(CO)18(.mu.4-S)(.mu.3-S) and two isomers of H2Os6(CO)17(.mu.4-S)(.mu.3-S)

Abstract

Cleavage of carbon-sulfur bonds in thiolato ligands in osmium carbonyl cluster compounds. The synthesis and structural characterization of H2Os6(CO)18(.mu.4-S)(.mu.3-S) and two isomers of H2Os6(CO)17(.mu.4-S)(.mu.3-S)