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Abstract
Organyl alkenyl sulfides of general formula RS(CH2)nCH=CH2 react with triethyl- and triethoxysilane in the presence of PdCl2(C6H5CN)2 and P(C6H5)3, with cleavage of the S-C bond and the formation of the corresponding Si-substituted organylthiosilanes RSSiR3' and disilthianes R3'SiSSiR3'. The reaction is accompanied by the disproportionation of the starting silanes R3'SiH with the formation of R4'Si. Hydrosilylation products were not detected.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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