Abstract

La reaction CH 3 (CH 2 ) 4 CO Co(CO) 4 +HCo(CO) 4 a lieu avec une cinetique du 2eme ordre. La vitesse est independante de la pression partielle de CO. Il y aurait homolyse reversible rapide du complexe acyl suivie d'un arrachement d'hydrogene de HCo(CO) 4

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