Abstract
The growing concern for environmental sustainability has created an urgent need for the development of innovative and environmentally friendly packaging materials. Among the various options available, clay-starch nanocomposites have emerged as a promising avenue for improving the barrier properties and mechanical strength of paper substrates. In this scientific paper the importance of clay-starch nanocomposite coatings on paper substrate and highlight the role of computer simulations, especially molecular dynamics, in elucidating their structural and functional properties. It has been shown that phyllosilicates with a layer charge < 0.4 electrons per stoichiometric unit can intercalate starch in the interlayer space, forming a barrier for water vapor in the covering layer. Phyllosilicates with a shell charge of >0.4 electrons per stoichiometric unit were not able to intercalate starch. Thus, clay-starchnanocomposites can provide limited water vapor transfer rates and can be recommended asa promising material for dry food packaging.
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