Abstract

Cases of chemical reactions following the electron transfer that have been solved so far for the galvanostatic method with current reversal (GMCR) have been summarized. Relations for the evaluation of kinetic parameters based on the measurement of transition time after the current reversal for sufficiently fast chemical reactions are indicated in four tables. Special attention is paid to reactions which cannot be followed by means of the galvanostatic method without current reversal. It is assumed that the reacting substances either undergo free diffusion or are reversibly adsorbed or totally accumulated on the electrode surface. Several new reaction schemes, not yet solved, have been included. Finally, directions for classification and verification of different types of chemical follow-up reactions are presented in two tables.

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