Abstract

The effect of vibration–rotation interaction on line intensities is treated semiclassically. Consideration of this effect enables one to determine the dipole moment function uniquely, and its classical treatment is both simpler and easier to visualize, although less precise, than the quantum-mechanical one. The calculation is performed for the fundamental, first, and second overtone bands, and the second overtone of CO is used as an example for the determination of M3 in the dipole moment function.

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