Clarification of nonlinear retardation factors for colloid-enhanced transport in porous media

Abstract

There have been a couple of contaminant retardation factors reported for the three-phase (aqueous, solid, and colloid) groundwater system. However, the retardation factor has often been presented by itself and not incorporated into the relevant transport equation, particularly when derived from the mass fraction approach. This may cause a misunderstanding of the retardation factor especially for the systems where multi-phases exist due to the presence of colloids and/or nonlinear sorption processes are involved. It is, therefore, necessary to clarify the form of the nonlinear retardation factor along with the relevant transport equation in the multi-phase system. Alternative forms of the retardation factor and relevant transport equation for specific conditions are presented in various combinations of the nonlinearity of involved sorption mechanisms. The retardation factors for specific conditions are compared with the ones available in the literature. The results indicate that more caution should be given in applying the retardation factor in order to explore contaminant transport in the multi-phase system where any nonlinear sorption is involved. Finally, presentation of the retardation factor along with the relevant transport equation in this study would help prevent possible misuse of the retardation factor in investigating contaminant transport in the multi-phase system.