Abstract
A group of 1–3 type piezoelectric Pb (Mg1/3Nb2/3)O3-PbTiO3/polyvinylidene fluoride (PMN-PT/PVDF) composite sheets are prepared using a complex two-step hot-pressing method. Then the molecular structure model of piezoelectric materials and an inverse piezoelectric simulation of the composites are performed to express the horizontal compression, indicating the clamping activity of ferroelectric PVDF on PMN-PT. As such, this composite sheet possesses a high dielectric permittivity (εr) of 560 at 100 Hz for its compacted connecting of two phases. After polarization, a very large piezoelectric coefficient (d33) of 1125 pC/N and a considerable electromechanical coupling factor (kt) of 0.43 is obtained in PMN-PT/PVDF sheet with a proper aspect ratio of 1.4 and a thickness of 2.1 mm, further indicating that promoting effect of PVDF matrix on the strain in Z-direction of PMN-PT. The result shows that ferroelectric PVDF serving as polymer matrix favors the electromechanical coupling effect, and may provide a prospect of the potential application of PMN-PT/PVDF composite in sensor or transistor for matrix ultrasonic probes.
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