Cis–transIsomers of PtX4L2(X= halogen andL= neutral ligand):trans-bis(dimethyl sulfide)tetraiodidoplatinum(IV)

Abstract

The octahedral title complex, [PtI4(C2H6S)2] or trans-PtI4(dms)2 (dms is dimethyl sulfide), crystallizes in the monoclinic space group P2(1)/n (Z = 2), with molecular symmetry C(i), which is the most frequently occurring point group for trans-PtX4L2 {56%, 28 structures in the Cambridge Structural Database (CSD) [Allen (2002). Acta Cryst. B58, 380-388]}, followed by C(1) (22%, 11 structures). The complexes form a puckered pseudo-hexagonal layer in the (10(1)) plane, and the layers are stacked with an interplanar distance of 7.10 A. Density functional theory (DFT) calculations on an isolated complex with the observed parameters as a starting structure converged to C(2h). Constraints to C(i) on the observed geometry give 3-4 kJ mol(-1) higher energy compared with C(2h). DFT calculations on [PtCl4(PzH)2] (PzH is pyrazole), reported in the CSD in both the cis and trans forms, show an energy difference of 21 kJ mol(-1) in favour of the trans complex. A CSD search for PtX4L2-type complexes, where X is a halogen and L is a ligand with a donor atom from group 14, 15 or 16, indicated a preferred trans geometrical arrangement, with a total fraction of 68%. The dominating crystal packing operators for the trans complexes are an inversion centre combined with a screw axis/glide plane (48%), followed by an inversion centre alone (28%).