Abstract

The title compound, [PtCl2(C18H12Cl3P)2]·C2H3N, packs as monomeric units with a square-planar geometry around the PtII atom. The two tris­(4-chloro­phen­yl)phosphane ligands are coordinated in a cis orientation, with P—Pt—P and Cl—Pt—Cl angles of 99.36 (2) and 88.02 (2)°, respectively. In the crystal, C—H⋯N inter­actions are observed between the phenyl rings and the acetonitrile solvent mol­ecules.

Highlights

  • Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa

  • The two tris(4-chlorophenyl)phosphane ligands are coordinated in a cis orientation, with P—Pt—P and Cl—Pt—Cl angles of 99.36 (2) and 88.02 (2), respectively

  • C—H N interactions are observed between the phenyl rings and the acetonitrile solvent molecules

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Summary

Structure Reports

Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa. R factor = 0.023; wR factor = 0.052; data-to-parameter ratio = 21.2. The title compound, [PtCl2(C18H12Cl3P)2]C2H3N, packs as monomeric units with a square-planar geometry around the. The two tris(4-chlorophenyl)phosphane ligands are coordinated in a cis orientation, with P—Pt—P and Cl—Pt—. Cl angles of 99.36 (2) and 88.02 (2) , respectively. C—H N interactions are observed between the phenyl rings and the acetonitrile solvent molecules

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