Abstract
In the title compound, [Zn(2,2′,2′′-tpa)2(H2O)2](ClO4)2 (2,2′,2′′-tpa is 2,2′,2′′-tripyridylamine, C15H12N4), the Zn center lies on a twofold axis and is coordinated octahedrally by two water molecules and two bidentate 2,2′,2′′-tpa ligands. The perchlorate anions are linked to the coordinated water molecules in the complex cations via O—H⋯O hydrogen bonds.
Highlights
In the title compound, [Zn(2,20,200 -tpa)2(H2O)2](ClO4)2 (2,20,200 -tpa is 2,20,200 -tripyridylamine, C15H12N4), the Zn center lies on a twofold axis and is coordinated octahedrally by two water molecules and two bidentate 2,20,200 -tpa ligands
The perchlorate anions are linked to the coordinated water molecules in the complex cations via O—H O hydrogen bonds
By using the neutral ligand, 2,2′,2′′-tripyridylamine, we report here the synthesis and crystal structure of the title compound, diaquabis(2,2′,2′′-tripyridylamine)zinc(II) bis(perchlorate)
Summary
Data collection cis-Diaquabis(2,20 ,20 0 -tripyridylamine)zinc(II) bis(perchlorate). Jiangsu Key Lab of Organic Electronics & Information Displays, Institute of Advanced. H atoms treated by a mixture of independent and constrained refinement max = 0.86 e Å3. R factor = 0.057; wR factor = 0.143; data-to-parameter ratio = 12.3. (2,20 ,200 -tpa is 2,20 ,200 -tripyridylamine, C15H12N4), the Zn center lies on a twofold axis and is coordinated octahedrally by two water molecules and two bidentate 2,20 ,200 -tpa ligands. The perchlorate anions are linked to the coordinated water molecules in the complex cations via O—H O hydrogen bonds
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