Abstract
The title compound, [Ru(CHO2)(C10H8N2)(C15H11N3)(CO)]PF6 or cis-[Ru(bpy)(η2-tpy)(CO)(COOH)]PF6 (where bpy is 2,2′-bipyridyl and tpy is 2,2′:6′,2′′-terpyridyl), has distorted octahedral geometry about the Ru atom, a bidentate terpyridyl ligand and a fully chelated bipyridyl ligand. The terminal carbonyl and carboxyl groups are cis. The Ru—C—O angle (terminal carbonyl) is distorted from linearity [173.7 (4)°] by the pendant pyridyl group of the N,N′-bound tpy ligand, which is hydrogen bonded to the hydroxyl proton of the carboxyl group.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section C Crystal Structure Communications
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
