Abstract

In the title compound, cis-[PdCl2{P(C4H3O)3}2]·0.5CH2Cl2, where P(C4H3O)3 is tri-2-furylphosphine, the PdII centre shows a slightly distorted square-planar geometry with the two chloro ligands in cis positions. Pd—P bond lengths are 2.2329 (10) and 2.2613 (9) A and Pd—Cl bond lengths are 2.3393 (9) and 2.3501 (10) A. The P—Pd—Cl angles are 89.07 (4) and 175.28 (4)°. The average effective cone angle for the tri-2-furylphosphine was calculated to be 149°.

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