Abstract

The structural features of the title complex, [SnCl 2 (C 5 H 10 NS 2 ) 2 ], are significantly different to those of the complexes Me 2 Sn(S 2 CNR 2 ) 2 that have been structurally characterized so far. In the title complex the geometry around the Sn atom is cis-octahedral with a Cl-Sn-Cl angle of 91.85 3) o and an average Sn-Cl bond length of 2.404 (7) A. Bothdithiocarbamato groups behave as bidentate chelating ligands with an average Sn-S bond length of 2.539 (6) A and an average S-Sn-S bond angle of 71.01 (2) o

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