Abstract
The crystal structure of the title compound, [IrCl2(C12H8N2)2]PF6, contains a monomeric [IrCl2(phen)2]+ cation (phen is 1,10-phenanthroline) and a hexafluorophosphate anion. The iridium(III) ion is coordinated by four N atoms from two phen ligands [mean Ir—N distance 2.050 (5) A] and two Cl atoms [Ir—Cl = 2.343 (1) A], forming a distorted octahedral environment.
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