Abstract
The preparation and crystal structure of the title compound, cis-dichloro[6,9-dioxa-3,12-dithiabicyclo[12.4.0]octadeca-14,-16,18(1)-triene-S,S′]palladium(II), [PdCl2(C14H20O2S2)], are described. The Pd atom has a square-planar environment, coordinated to two S atoms of the dithiadioxa macrocycle and to two Cl− ions. The non-coordinating O atoms are oriented away from the metal coordination plane. Upon complexation, a bicyclic chelate structure, which consists of a seven- and an eleven-membered ring, is formed.
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Schedule a callMore From: Acta crystallographica. Section C, Crystal structure communications
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