Abstract
The Pt atom has a slightly distorted square-planar coordination in both title compounds, cis-[PtBr 2 (C 2 H 6 OS) 2 ] and trans-[PtI 2 (C 2 H 6 OS) 2 ], with the dimethyl sulfoxide ligands bonded via their S atoms. The bond distances to platinum in the bromo compound are Pt-Br 2.441(1) and 2.447(2), and Pt-S 2.254(2) and 2.245 (2) A, and in the centrosymmetric iodo complex are Pt-I 2.6111 (9) and Pt-S 2.289 (2) A.
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