Abstract
In the title complex, [Ni(C12H8N2)2(H2O)2](C7H4O6S)·4H2O, the cation interacts with the anion and uncoordinated water molecules through hydrogen bonding with the coordinated water molecules, giving rise to a hydrogen-bonded sheet architecture. In the cation, the Ni atom exists in an octahedral geometry with two cis-arranged water ligands.
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