Cis-Di-µ-chlorobis{(1S,4S)-2-[benzylimino]-7,7-dimethylbicyclo[2.2.1]heptylmethyl-C,N}dipalladium(II) and trans-dichlorobis{(1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane-N}palladium(II): Syntheses and structural studies

O A Zalevskaya ,Ya A Gur’Eva,П А Слепухин ,А В Кучин

doi:10.1134/s1070328415080114

Cis-Di-µ-chlorobis{(1S,4S)-2-[benzylimino]-7,7-dimethylbicyclo[2.2.1]heptylmethyl-C,N}dipalladium(II) and trans-dichlorobis{(1S,4S)-2-[benzylimino]-1,7,7-trimethylbicyclo[2.2.1]heptane-N}palladium(II): Syntheses and structural studies

O A Zalevskaya , Ya A Gur’Eva + Show 2 more

https://doi.org/10.1134/s1070328415080114

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Journal: Russian Journal of Coordination Chemistry	Publication Date: Aug 1, 2015
Citations: 1

Affiliation: Syktyvkar State University, Russian Academy of Sciences, Institute of Organic Synthesis

#Cyclopalladated Ligands #Pd Bond + Show 8 more

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Abstract

Enantiomerically pure palladium complexes of different compositions, binuclear palladacycle containing the (sp3)C–Pd bond (I) and mononuclear coordination palladium compound (II), are synthesized and studied by X-ray diffraction analysis. In complex I, the cyclopalladated ligands are in the cis position (CIF file CCDC no. 1049805 (I)). In compound II, the ligands coordinated through the monodentate mode occupy the trans position (CIF file CCDC no. 1049806 (II)).

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