Abstract
In the title compound, cis-ammine(benzohydrazide-N')dichloroplatinum(II), cis-[PtCl 2 (C 7 H 8 N 2 O)(NH 3 )], the benzoylhydrazine ligand is bonded to the Pt atom through its amino group. The Pt-Cl and Pt-N distances are in the ranges 2.293 (5)-2.318 (5) and 2.01 (1)-2.08 (1) A, respectively. The arrangement of molecules in the monoclinic unit cell approximates P2 1 /c space-group patterns; however, the true spacegroup symmetry is P2 1 . The two crystallographically independent molecules have significantly different conformations about the Pt-N(hydrazine) bond. The structure is held together by a complicated network of N-H...O and N-H...Cl hydrogen bonds
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