Abstract
Circularly polarized luminescence spectroscopy has been used to study the ternary complexes formed by europium(III) ..beta..-diketonate complexes and methyl p-tolyl sulfoxide. Adduct complexes having 1:1 and 1:2 chelate/substrate stoichiometries were formed, depending on the degree of fluorination in the ..beta..-diketone chelate rings. Enhancements in the Eu(III) luminescence intensities and lifetimes were used to evaluate the formation constants of the adduct complexes. In the 1:1 adduct complexes, the Eu(III) chirally was determined primarily by vicinal effects. In the 1:2 adduct complexes, evidence was obtained that indicated that presence of weak configurational effects due to geometrical isomerism. 21 references, 6 figures, 4 tables.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
