Abstract

The physico-chemical and performance characteristics of lubricant-type colloidal systems depend to a great extent on their aggregative state. Thermodynamic sorption parameters determined by means of reversed-phase chromatography, are proposed for assessing the aggregative state of colloidal systems. It is shown that the retention characteristics and thermodynamic parameters of sorption may serve as a measure of interphase and surface tension, which predetermine the free surface energy of heterogeneous systems.

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