Abstract
With the aim of understanding the differences in the behavior of deep eutectic solvents (DESs) and room temperature ionic liquids (RTILs) in terms of their structure, dynamics, and intra- and intermolecular interactions, three different ILs and one DES having similar functionalities (hydroxyl) have been investigated by using both ensembled average and single-molecule spectroscopic techniques. Specifically, for this purpose, a choline chloride based DES (ethaline) and three hydroxyl functionalized ILs (1-(2-hydroxyethyl)-3-imidazolium bis(trifluoromethanesulfonyl)imide ([OHEMIM][NTF2]), N-(2-hydroxyl ethyl)-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([OHEMPy][NTf2]), and N-(2-hydroxyethyl)-N,N-dimethylpropan-1-aminium bis(trifluoromethanesulfonyl)imide ([OHC3CH][NTf2])) are employed and investigated by EPR, time-resolved fluorescence, NMR and FCS studies. Estimation of polarity through EPR spectroscopy has revealed that the hydroxyl ILs employed in these studies are hyper-polar (close to water) in nature, whereas the polarity of the DES is found to be close to those of aliphatic polyhydroxy-alcohols. Interestingly, both time-resolved fluorescence anisotropy and FCS studies on these systems have suggested that the hydroxyl ILs are more dynamically heterogeneous than the DES. More interestingly, PFG-NMR measurements have indicated that the fluid structure of ethaline is relatively more associated as compared to those of the ILs despite the fact that all the cations have the same hydroxyl functionalities. All these investigations have essentially demonstrated that, despite having similar functionalities, both the DES and hydroxyl ILs employed in the present study exhibit microscopic behaviours that are significantly different from each other, indicating the interplay of various intermolecular interactions within the constituent species in governing the behaviours of these solvent systems.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
