Abstract
The non-aqueous solution of chlorous acid is a versatile chlorinating agent for aromatic compounds, e.g. alkylbenzenes, anisoles, and acetanililides. It is also an effective chlorine-substitute for the conversion of aryl bromides into aryl chlorides under mild conditions. The stoichiometry of the chlorination reaction is ArH+3HOClO→ArCl+2ClO2+2H2O, and the mode of dissociation of chlorous acid in dichloromethane is 3HOClO→HOCl+2ClO2+H2O.
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Schedule a callMore From: Monatshefte für Chemie und verwandte Teile anderer Wissenschaften
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