Abstract
The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent molecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetrahedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands. The thiosemicarbazone acts as a monodentate ligand through its thione S atom. An intramolecular N—H⋯Cl hydrogen bond occurs in two of the independent molecules. In the crystal, the molecules are assembled through N—H⋯Cl hydrogen bonds, forming chains along [101].
Highlights
H atoms treated by a mixture of independent and constrained refinement max = 1.03 e Å 3
The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent molecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetrahedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands
The thiosemicarbazone acts as a monodentate ligand through its thione S atom
Summary
Rint = 0.055 a Department of Chemistry and Biochemistry, Jackson State University, Jackson, MS. University, Jackson, MS 39217-0510, USA, and cDepartment of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA. H atoms treated by a mixture of independent and constrained refinement max = 1.03 e Å 3. Key indicators: single-crystal X-ray study; T = 90 K; mean (C–C) = 0.005 Å; R factor =. The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent molecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetrahedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands. N—H Cl hydrogen bond occurs in two of the independent molecules. N—H Cl hydrogen bonds, forming chains along [101]
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