Abstract
In the title compound, [Cu(C6H5N2O)Cl(C6H6N2O)], the Cu atom is coordinated by one neutral and one deprotonated pyridine-2-carboxaldehyde oxime (pco) ligand, resulting in the formation of two five-membered CuN2C2 rings. Together with the additional coordinating chloride anion, the coordination polyhedron of copper is best described as a distorted square-pyramid, the distortion parameter being 0.288. The two organic ligands are linked by an intramolecular O—H⋯O hydrogen bond.
Highlights
In the title compound, [Cu(C6H5N2O)Cl(C6H6N2O)], the Cu atom is coordinated by one neutral and one deprotonated pyridine-2-carboxaldehyde oxime ligand, resulting in the formation of two five-membered CuN2C2 rings
Together with the additional coordinating chloride anion, the coordination polyhedron of copper is best described as a distorted square-pyramid, the distortion parameter being 0.288
The two organic ligands are linked by an intramolecular O—H O
Summary
See: Addison et al (1984); Afrati et al. (2005); Korpi et al (2005); Pearse et al (1989); Stamatatos et al (2006). The two organic ligands are linked by an intramolecular O—H O hydrogen bond
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