Abstract
The asymmetric unit of the title compound, [Pt(C5H4NOS)Cl(C2H6OS)], contains two independent complex molecules having similar geometries. Each PtII atom is four-coordinated in a distorted square-planar geometry by S and O atoms of one pyridine N-oxide ligand, the S atom of one dimethyl sulfoxide molecule and one terminal Cl− ion. The molecules are linked into a three-dimensional framework by C—H⋯O and C—H⋯Cl hydrogen bonds.
Highlights
The asymmetric unit of the title compound, [Pt(C5H4NOS)Cl(C2H6OS)], contains two independent complex molecules having similar geometries
Each PtII atom is four-coordinated in a distorted square-planar geometry by S and O atoms of one pyridine N-oxide ligand, the S atom of one dimethyl sulfoxide molecule and one terminal ClÀ ion
The molecules are linked into a three-dimensional framework by C—HÁ Á ÁO and C— HÁ Á ÁCl hydrogen bonds
Summary
The molecules are linked into a three-dimensional framework by C—HÁ Á ÁO and C— HÁ Á ÁCl hydrogen bonds. Related literature For biological activities of platinum, see: Weiss & Christian (1993); Loehrer et al (1988); For biological activities of Noxide derivatives, see: Bovin et al (1992); Katsuyuki et al (1991); Leonard et al (1955); Lobana & Bhatia (1989); Symons & West (1985). See: Jebas et al (2005); Ravindran et al (2008); Dyksterhouse et al (2000); Ohms et al (1982); Ravindran et al (2008). For bond-length data, see: Allen et al (1987)
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