Abstract

The potential tridentate Schiff base ligand 2-[1-(2-pyridyl­methyl­imino)eth­yl]pyrrole (HL) was synthesized from the condensation of 2-acetyl­pyrrole with 2-amino­methyl­pyridine. The title compound, [Cu(C12H12N3)Cl], was synthesized from HL and copper(II) chloride using triethyl­amine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N3Cl coordination.

Highlights

  • The potential tridentate Schiff base ligand 2-[1-(2-pyridylmethylimino)ethyl]pyrrole (HL) was synthesized from the condensation of 2-acetylpyrrole with 2-aminomethylpyridine

  • ion is bound to three N atoms of the deprotonated tridentate ligand

  • This work was supported by the Natural Science Foundation of the Department

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Summary

Bruker SMART APEX CCD diffractometer

R factor = 0.050; wR factor = 0.124; data-to-parameter ratio = 13.9. The potential tridentate Schiff base ligand 2-[1-(2-pyridylmethylimino)ethyl]pyrrole (HL) was synthesized from the condensation of 2-acetylpyrrole with 2-aminomethylpyridine. HL and copper(II) chloride using triethylamine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N3Cl coordination

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