Abstract
The potential tridentate Schiff base ligand 2-[1-(2-pyridylmethylimino)ethyl]pyrrole (HL) was synthesized from the condensation of 2-acetylpyrrole with 2-aminomethylpyridine. The title compound, [Cu(C12H12N3)Cl], was synthesized from HL and copper(II) chloride using triethylamine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N3Cl coordination.
Highlights
The potential tridentate Schiff base ligand 2-[1-(2-pyridylmethylimino)ethyl]pyrrole (HL) was synthesized from the condensation of 2-acetylpyrrole with 2-aminomethylpyridine
ion is bound to three N atoms of the deprotonated tridentate ligand
This work was supported by the Natural Science Foundation of the Department
Summary
R factor = 0.050; wR factor = 0.124; data-to-parameter ratio = 13.9. The potential tridentate Schiff base ligand 2-[1-(2-pyridylmethylimino)ethyl]pyrrole (HL) was synthesized from the condensation of 2-acetylpyrrole with 2-aminomethylpyridine. HL and copper(II) chloride using triethylamine as a base to deprotonate the pyrrole NH group. The title compound is a monomer and the central copper(II) ion is bound to three N atoms of the deprotonated tridentate ligand and to one chloride ion in a square-planar N3Cl coordination
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