Chitosan capped trimetallic nanoparticles: Synthesis and their Congo red adsorbing activities

Abstract

Chitosan capped Fe0-based Fe-Pd-Ir (Chi-Fe-Pd-Ir) tri-metallic nanoparticles were fabricated using metal displacement method in presence of sodium borohydride. The preliminary indications of Fe0 production were the appearance of pale yellow color with ferric nitrate, NaBH4, and chitosan. Chitosan was detected by using ninhydrin color test, thermal gravimetric analysis and measurement of relative viscosity. The average molecular weight of chitosan and Chi-Fe-Pd-Ir decreased with increased potassium persulfate concentration. Chi-Fe-Pd-Ir used as an adsorbent for the removal of Congo red. The sorption equilibrium data were fitted into Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherms (DRK). The maximum monolayer adsorption capacity (Q0max), and sorption intensity (n) were estimated to be 93.4 mg/g and 2.0, respectively, from Langmuir and Freundlich adsorption isotherm models. The mean free energy was calculated by using DRK isotherm to be 0.15 kJ/mol. Sorption parameters indicate that the Congo red adsorbed on the surface of Chi-Fe-Pd-Ir through monolayer formation via physisorption process. The adsorption of CR on Chi-Fe-Pd-Ir was in good agreement with the Langmuir adsorption isotherm and pseudo-second-order kinetic model. Protonated amino group of chitosan was also responsible for the adsorption of anionic CR along with the Fe-Pd-Ir NPs.