Chitosan and silica nanoparticles-modified xanthan gum-derived bio-nanocomposite hydrogel film for efficient uptake of methyl orange acidic dye

Abstract

In this contribution, a bio-nanocomposite hydrogel film (CS/XG.SiO2) of chitosan/silica NPs-modified xanthan gum was prepared via a facile solution casting blending approach and utilized to capture the anionic methyl orange (MO) from aqueous solution. A Taguchi standard method was used to optimize the hydrogel nanocomposite synthesis reaction conditions after comprehensive characterization using various techniques. Under various operating parameters, the hydrogel biofilm was tested for its effectiveness in adsorbing MO dye in a batch process. In agreement with Langmuir isotherm, the CS/XG.SiO2 biofilm was capable of adsorbing MO at a maximum capacity of 294 mg/g at pH 5.30, contact time 45 min, temperature 25 °C, and concentration (C0) 50 mg/L. Pseudo-second-order model and adsorption kinetics data well matched. The thermodynamic data indicate that adsorption occurred spontaneously and exothermically. The main mechanisms driving the adsorption are electrostatic interactions and hydrogen bonding between the CS/XG.SiO2 nanocomposite and the dye. Furthermore, the biofilm is regenerative, allowing for up to five reuses while maintaining a 75 % dye removal efficiency. This study highlights that the CS/XG.SiO2 hydrogel nanocomposite is an inexpensive, reusable, and eco-friendly bio-adsorbent that is capable of anionic dye adsorption.