Chiroptical Elastomer Film Constructed by Chiral Helical Substituted Polyacetylene and Polydimethylsiloxane: Multiple Stimuli Responsivity and Chiral Amplification.

Abstract

Chiral and circularly polarized luminescence (CPL) materials with multiple stimuli responses have become a focus of attention. Meanwhile, elastomers have found substantial applications in a wide variety of fields. However, how to design and construct chiral elastomers, in particular CPL-active elastomers, still remains an academic challenge. In the present study, chiral helical substituted polyacetylene is chemically bonded with polydimethylsiloxane (PDMS) by hydrosilylation to form a chiroptically active elastomer. A CPL-active film was further fabricated by adding achiral fluorophores. Compared with the corresponding chiral helical polymer, the chiral films show much enhanced thermal stability in terms of chiroptical properties. The films also demonstrate reversible tunability in optical activity and CPL property when being subjected to a stretching-restoring process and exposed to a solvent like toluene. Further, noticeable chiral amplification is observed when the chiral PDMS film is superimposed with a pure PDMS film. This interesting finding is proposed to be due to the photoreflectivity of PDMS. This study provides an alternative strategy to exploit novel CPL-active elastomer materials with multiple stimuli responsivity and tunability, which may open up new opportunities for developing novel chiroptical devices.