Chiromagnetic Plasmonic Nanoassemblies with Magnetic Field Modulated Chiral Activity.

Abstract

Chiral plasmonic nanoassemblies, which exhibit outstanding chiroptical activity in the visible or near-infrared region, are popular candidates in molecular sensing, polarized nanophotonics, and biomedical applications. Their optical chirality can be modulated by manipulating chemical molecule stimuli or replacing the building blocks. However, instead of irreversible chemical or material changes, real-time control of optical activity is desired for reversible and noninvasive physical regulating methods, which is a challenging research field. Here, the directionally and reversibly switching optical chirality of magneto-plasmonic nanoassemblies is demonstrated by the application of an external magnetic field. The gold-magnetic nanoparticles core-satellite (Au@Fe3 O4 ) nanostructures exhibit chiral activity in the UV-visible range, and the circular dichroism signal is 12 times greater under the magnetic field. Significantly, the chiral signal can be reversed by regulating the direction of the applied magnetic field. The attained magnetic field-regulated chirality is attributed to the large contributions of the magnetic dipole moments to polarization rotation. This magnetic field-modulated optical activity may be pivotal for photonic devices, information communication, as well as chiral metamaterials.