Abstract
Encapsulation of chiral ruthenium porphyrin [RuII(D4-Por*)CO] in modified mesoporous silica supports such as MCM-41 and MCM-48 achieves active catalysts for asymmetric epoxidation of alkenes by 2,6-dichloropyridine N-oxide and intramolecular cyclopropanation, which is the first example of chiral metalloporphyrin supported on ordered molecular sieves.
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