Abstract

Abstract Chiral recognition of α-amino esters was examined using the homochiral helical dimer of the zinc complex of linear tetrapyrrole (zinc bilinone) as a host. 1H NMR and thermodynamic studies indicated that favorable (Phe–Ome and Leu–Ome) or unfavorable (Asp–(Ome)2) interactions of the side chain of α-amino esters with zinc bilinone lead to enantioselectivity.

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