Abstract
Abstract A new chiral mononuclear Dy(III) complex, [Dy((-)-pbipy)(pdtc)3] (1) (pbipy = 4,5-pinene-2,2′-bipyridine, pdtc = pyrrolidine-dithiocarbamate) has been synthesized and structurally characterized. Magnetic studies show that complex 1 exhibits field-induced single-ion magnet behavior with τ0 = 4.2 × 10−7 s and Ueff/k = 56.7 K, which is the first example of homochiral complex derived from S-donor pyrrolidine-dithiocarboxylate with slow magnetic relaxation.
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