Chiral Homobimetallic Palladium(II) Complexes Composed of Chirality-Organized Quinonediimines Bearing Amino Acid Moieties

Abstract

The chirality-organized quinonediimine derivatives bearing amino acid moieties were demonstrated to react with 2 molar equiv. of Pd(OAc)2, resulting in the formation of the chiral homobimetallic palladium(II) complexes. The crystal structures of the chiral conjugated complexes revealed the coordination of the quinonediimine nitrogen to a palladium center and a chiral propeller twist conformation of the π-conjugated backbone. The mirror image relationship of the CD signals around the quinonediimine moieties in acetonitrile was observed between l- and d-derivatives, indicating the preservation of the chirality-organized structures even in a solution.