Abstract
A chiral crown ether incorporating a methyl α-d-mannopyranoside unit displayed pronounced enantioselection of amino acids in partition liquid chromatography experiments involving solvent systems of limited miscibility: water–ethanol–2,2,4-trimethylpentane. The same system has been used for amino acid transport across a liquid membrane containing the crown ether, and in liquid–liquid extraction experiments. Remarkable enantioselection has been noted for amino acids in all the processes studied.
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