Abstract
An efficient chiral Brønsted acid-catalyzed conjugate addition of indoles to azadienes has been successfully developed, which enables a facile approach to optically active hetero-triarylmethanes with excellent enantioselectivities and broad substrate scope. This chiral Brønsted acid catalytic system provides a new opportunity for the development of asymmetric reactions of azadienes. An efficient chiral Brønsted acid-catalyzed conjugate addition of indoles to azadienes has been successfully developed, which enables a facile approach to optically active hetero-triarylmethanes with excellent enantioselectivities and broad substrate scope. This chiral Brønsted acid catalytic system provides a new opportunity for the development of asymmetric reactions of azadienes.
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