Chiral breathing-valley locking in two-dimensional kagome lattice Ta3I8

Abstract

The exploration of valley-related physics is essential to the development and refinement of valleytronics. Here, a paradigm called chiral breathing-valley locking (CBVL) is proposed, in which two chiral “breathing” phases are completely locked to their valley indexes. Utilizing first-principles calculations, a two-dimensional (2D) kagome lattice with large spontaneous valley polarization (VP), namely, monolayer Ta3I8, is proposed to realize CBVL. There are two breathing phases with chiral symmetry in Ta3I8, and they can change to each other under some conditions. The valley indexes change between “−K” and “K” along the breathing of the two chiral symmetric phases, so CBVL can be obtained. Remarkably, the VP is up to 199.7 meV, so CBVL can cause the obvious switching of the anomalous valley Hall effect (AVHE). Additionally, a 2D Janus Kagome structure TaI4X4 is constructed to confirm experimentally the feasibility of electric field modulation on the CBVL. The built-in electric field and the breathing mode can mutually influence each other in TaI4X4, which provides a synergistic regulation of the AVHE. Our findings broaden the horizon for exploring AVHE materials and provide a platform for future valleytronic applications.