Abstract
A catalyst system of Rh 6(CO) 16 and N, N, N′, N′-tetramethyl-1,3-propanediamine (TMPDA) or aminated polystyrene achieves highly chemoselective reduction of aromatic nitro groups in the presence of olefinic, ester, and halogeno functions using CO and H 2O. Use of the aminated polystyrene leads to easy isolation of amino products from reaction mixtures by forming a polymer-bound Rh 6 carbonyl cluster.
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