Abstract

AbstractIn this work, we report a chemoselective C(CO)−C bond cleavage of aryl methyl ketones in the presence of molecular iodine. The in situ generated keto aryl fragment combined with o‐aminobenzyl amines to give quinzolines through a C−H/N−H oxidative tandem cyclization. Various derivatives of quinazolines could be synthesized in good to excellent yields under transition‐metal‐ and additive‐free conditions.

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