Abstract

Diaryliodonium salts are versatile arylating agents but generally feature poor atom economy. In this issue of <i>Chem</i>, Olofsson and co-workers describe a novel chemoselective S<sub>N</sub>Ar reaction that sets up a second <i>in situ</i> arylation and incorporates the iodoarene component in a cascade arylation with excellent atom economy.

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