Abstract
Kinetic analysis by the method of proportional equations is widely used; this study provides the chemometric basis of some of the general knowledge in this field. Analytical expressions for optimum measurement time and minimum rate constant ratio as a function of the accepted error are derived. Both kinetic schemes, of monitoring the reactants and products, are considered and compared. It is shown that the selection of optimum time is critical only when rate constant ratio is close to unity, and quantitative criteria are provided.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.