Abstract
Electrochemical fluorinations of C(sp3 )-H bonds with a nucleophilic fluoride source have been accomplished in a chemo- and site-selective fashion, avoiding the use of electrophilic F+ sources and stoichiometric oxidants. The introduced metal-free strategy exhibits high functional group tolerance, setting the stage for late-stage fluorinations of biorelevant motifs. The synthetic utility of the C(sp3 )-H fluorination was reflected by subsequent one-pot arylation of the generated benzylic fluorides.
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