Abstract
The three azirinyl complexes (R = CN, CHCH2, Ph) are obtained from deprotonation of isonitrile complexes. For R = Ph, three isomers including 1H- and 2H-azirinyl complexes are observed at low temperature. Insertion of CO groups of acetone, aldehyde, ester, and amide into the azirinyl ligand follows regiospecificity opposite that in the photochemical-induced insertion of the organic azirine system.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
