Abstract
The interactions of carbon monoxide and carbon dioxide with chromocene supported on solica were studied by infrared spectroscopy. Chemisorption of CO resulted in the formation of various carbonyl complexes. The nature of these complexes was dependent upon CO pressure, Cr loading, adsorption time, and dehydration temperature of the silica. Monocarbonyl complexes were the major species formed at a low pressure (0.02 Torr)
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