Abstract
Triruthenium imido cluster Ru3(CO)10(μ3-NPh)(1) reacts with tungsten hydride LW(CO)3H to afford heterometallic imido clusters LWRu2(CO)8(μ-H) (μ3-NPh), L=Cp, (IIa); L=Cp*, (IIb), whereas the respective phosphinidene complexes LWRu2(CO)8(μ-H)(μ3-PPh), L=Cp, (IXa); L=Cp*, (IXb), were generated via reaction of Ru3(CO)10(μ-H)(μ-PPh2) with CpW(CO)3H and with CP*W(CO)3H followed by thermolysis in the presence of carbon monoxide. Their molecular structure, solution dynamics, and the subsequent reaction with hexafluoro-2-butyne are presented.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
