Abstract
Rotational epitaxy of an overlayer along a non-symmetry direction of the substrate has been observed as a mechanism for the accommodation of lattice mismatch in rigid thin films. We have examined the adsorption and rotational epitaxy of Li on the Ru(001) surface using low energy electron diffraction and thermal desorption spectroscopy. At 80 K, commensurate (2×2) and (√3×√3)R30° phases were observed at coverages below 0.33 monolayer. At higher coverages, the Li layer orientation rotates relative to the substrate as the interatomic spacing of the layer is compressed. This behavior is qualitatively similar to that observed for Na on Ru(001), but differences were observed which may suggest that Li overlayers are less rigid than Na overlayers.
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